The Fujita Laboratory

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A paper on the expression of unique molecular recognition abilities through host-in-host complexation by K. Iizuka and Dr. H. Takezawa et al. has been published as a Very Important Paper in Angew. Chem. Int. Ed.! (open access)
[Link]
A paper on the synthesis of an expanded M₉L₆ cage and its encapsulation ability toward medium-sized molecules (MW > 1000) has been published (open access) in J. Am. Chem. Soc. ! [Link]
A paper on new workflow for the structure elucidation of trace amount natural products by C. Park, Dr. N. Wada, and Dr. T. Mitsuhashi et al. has been published in Chem. Lett. [Link]
A paper on single-molecule encapsulation of proteins in coordination cages by R. Ebihara (D2) and Dr. T. Nakama has been published in Angew. Chem. Int. Ed.[Link]
A paper on the precise construction of discrete four-stranded β-sheet by E. Tsunekawa (D3) and Dr. T. Sawada has been published in Angew. Chem. Int. Ed.[Link]
A paper on MD simulations of the denaturation process of a protein in a coordination cage has been published in Chem. Lett. [link]
A paper on the conformational analysis of a natural product using the crystalline sponge method by Dr. Y. Jung, K. Kageyama, and Dr. T. Mitsuhashi et al. has been published in Chem. Eur. J. [Link]
A paper, which reveals that a viral terpene synthase, OILTS, can use broad metal ions as cofactors and shows metal-dependent biosynthesis, by Dr. Y. Jung and Dr. T. Mitsuhashi et al. has been published in Chem. Eur. J. [Link]
A paper on selective oligomerization and functionalization of arene in a coordination cage by Dr. H. Takezawa and K. Iizuka (D1) has been published as a Hot Paper in Angew. Chem. Int. Ed. [Link]
A paper on the structure analysis of amino acid derivatives using a formyl group-Installed crystalline sponge by B. Zhou, S. Utjapimuk, Dr. K. Yan, Dr. R. Dubey, and Dr. T. Mitsuhashi has been published in Chem. Asian J. [Link]
A paper on a terpene synthase from a giant virus by Y. Jung (D3) and Dr. T. Mitsuhashi has been published in J. Am. Chem. Soc. [Link]
This paper was highlighted on Nature Catalysis and Science IN THE PIPELINE.
A paper on symmetry-breaking reactions of symmetric calix[4]arenes in a coordination cage by K. Iizuka (D1) and Dr. H. Takezawa has been published in J. Am. Chem. Soc. [Link]
A paper on tetradehydro-Diels–Alder reactions in a coordination cage by Dr. G. Genov, Dr. H. Takezawa, H. Hayakawa et al. has been published in J. Am. Chem. Soc. [Link]
Highlighted by Chemistry World
A paper on constructing steric zipper interactions of β-sheets by E. Tsunekawa (D2), Dr. T. Sawada has been published in J. Am. Chem. Soc. [Link]
A collaborative paper with the Oguri Laboratory (School of Science, The Univ. of Tokyo) about stabilization and structure determination of synthetic alkaloid intermediates has been accepted in Angew. Chem. Int. Ed. [Link] [frontispiece]
A paper on NMR characterization of proteins utilizing spherical cages by A. Rossen (D3), R. Ebihara (M2) and Dr. T. Nakama has been published in Chem. Sci. [Link]
A collaborative paper with Dr. Tamura and Prof. Ishikita (School of Engineering, The Univ. of Tokyo) about theoretical studies on amide reactivity within a coordination cage has been published in Phys. Chem. Chem. Phys. [Link]
A paper on selective inclusion of rare-earth-metal ions in a coordination cage by R. Tabuchi, Dr. H. Takezawa et al. has been published in Angew. Chem. Int. Ed. (Hot Paper) [Link][ACIE Press Release]
Y. Domoto et al., a focused review on nanoscale syntheses based on metal...unsaturated-bond coordination in Coord. Chem. Rev. (A special issue "Current Coordination Chemistry in Japan") [Link] 50 days' free access here!
A paper on spirocyclization in a coordination cage by Dr. H. Takezawa et al. has been published in Angew. Chem. Int. Ed (selected as a Hot Paper). [Link][Highlighted by Synfacts]
Dr. Y. Domoto et al., Amplification of weak chiral inductions for excellent control over the helical orientation of discrete topologically chiral (M₃L₂)_n polyhedra, Chem. Sci. 2022, 13, 4372. [Link]
N. Wada (D3), Y. Jung (D1), Dr. T. Mitsuhashi et al., Solvent Effects in the Crystalline Sponge Method: Importance of Co-solvents for Ordering Absorbed Guests [Link]
J. Chen and Dr. T. Mitsuhashi et al. "Structure Analysis of Polyhalogenated Persistent Organic Pollutants by the Crystalline Sponge Method". [Link]
[BCSJ Review] H. Takezawa, M. Fujita, "Molecular Confinement Effects by Self-Assembled Coordination Cages" [Link]
[BCSJ Review] T. Sawada, M. Fujita, "Orderly Entangled Nanostructures of Metal–Peptide Strands"[Link]
A paper on Metal-Peptide Nonafoil Knots and Decafoil Supercoils by Y. Inomata and Dr. T. Sawada et al. is published in J. Am. Chem. Soc. and selected as Editor's Choice. [Link]
A paper on protein-encapsulation into the sherical cage by R. Suzuki and Dr. T. Nakama was published in Chem. [Link]
A paper on a visible-light responsive Ir cage with anion binding pockets by H. Sunohara, K. Koyamada, and Dr. H. Takezawa appeared on Chem. Commun. [Link]
A review article on the Crystalline sponge method is published on Angew. Chem. Int. Ed. [Link]
A paper on π-coordination-based highly-entangled cubic assembly by M. Abe and Dr. Y. Domoto et al. is published in J. Am. Chem. Soc. [Link][Highlight]
A paper on structural control of double β-helices by W. Iwasaki, Dr. M. Yamagami, and Dr. T. Sawada was appeared in the new Wiley journal, Nat Sci. [Link]
A paper on crystalline sponge method (absolute configuration determination from low ee compounds) was accepted in Agnew. Chem. Int. Ed. [Link] Congratulations to Anouk Rossen and ex-members of our group.
A paper on confinement of cationic substrates in a cationic cage with capping anions by R. Tabuchi, H. Sunohara, and Dr. H. Takezawa appeared on J. Am. Chem. Soc. [Link]
A paper on embedding molecular cages into inifinite crystalline lattices by M. Abe, K. Yamamoto, and Dr. Y. Domoto was just published in Chem. Sci. [Link]
A paper on observation of a chiral hemiacetal by Ms. Saito and Dr. Sawada published in Angew. Chem. Int. Ed. [Link]
[Review] T. Sawada & M. Fujita, "Folding and Assembly of Metal-Linked Peptidic Nanostructures", Chem, 2020, 6, 1861-1876. [Link]
A paper by Dr. Takezawa and Mr. Shitozawa on amide twisting by inclusion in a coordination cage appeared on Nat. Chem. [link][Faculty press]
Y. Tamura, H. Takezawa, M. Fujita, A Double-Walled Knotted Cage for Guest-Adaptive Molecular Recognition, J. Am. Chem. Soc. 2020, 142, 5504-5508. [Link]
A paper including results of the crystalline sponge project by Dr. T. Mitsuhashi and his co-workers (in collaboration with School of Fharmaceutical Sciences) was selected as a Hot Papaer in Agnew. Chem. Int. Ed. [Link]
A paper by M. Abe and Dr. Y. Domoto et al. on the coordination polyhedra with highly entangled faces induced by metal-acetylene interactions was selected as a Hot Paper in Angew Chem. Int. Ed. [Link]
Y. Inomata, T. Sawada, M. Fujita, Metal–Peptide Torus Knots from Flexible Short Peptides, Chem 2020, 6, 294-303. [Link]
A paper by Mr. Inomata (D1) and Dr. Sawada on the 24-crossing peptide [6]catenane appeared in Nat. Commun. [Faculty press]
A paper titled "Demethylenation of Cyclopropanes via Photo-Induced Guest-to-Host Electron Transfer in a M₆L₄ Cage" (Dr. Cullen and Dr. H. Takezawa) was selected as Very Important Paper (VIP) in Angew. Che. Int. Ed! [Link]
A paper on the crystalline sponge project (Mr. Wada (D1) in collaboration with J.-K. Weng Group (MIT)) has appreaed in Nat. Commun. [Link]
H. Takezawa, T. Kanda, H. Nanjo, M. Fujita, Site-Selective Functionalization of Linear Diterpenoids through U-Shaped Folding in a Confined Artificial Cavity, J. Am. Chem. Soc. 2019, 142, 5112-5115. [Link]

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