Lab. Members
- Yasuhide INOKUMA
- Assistant Professor
Profile
2004. 3 B.S. Kyoto University
2006. 3 M.S. Kyoto University
2009. 3 Ph.D. Kyoto University
2009. 4- Assistant Professor, The University of Tokyo
Awards
2007.9 Annual Meeting on Photochemistry 2007 Student Presentation Award
2009.3 CSJ Student Presentation Award 2009
2012.2 The University of Tokyo – GCOE – Chemistry Innovation:
Overseas Lectureship Award
2006. 3 M.S. Kyoto University
2009. 3 Ph.D. Kyoto University
2009. 4- Assistant Professor, The University of Tokyo
Awards
2007.9 Annual Meeting on Photochemistry 2007 Student Presentation Award
2009.3 CSJ Student Presentation Award 2009
2012.2 The University of Tokyo – GCOE – Chemistry Innovation:
Overseas Lectureship Award
List of Publications
"Reagent-Installed Capsule Network: Selective Thiocarbamoylation of Aromatic Amines in Crystals with Pre-installed CH3NCS"
Y. Inokuma, G.-H. Ning, M. Fujita
Angew. Chem. Int. Ed. 2012, 51, 2379-2381.
"Bimolecular Reaction via the Successive Introduction of Two Substrates into the Crystals of Networked Molecular Cages"
Y. Inokuma, N. Kojima, T. Arai, M. Fujita
J. Am. Chem. Soc. 2011, 133, 19691-19693.
"Diels–Alder via Molecular Recognition in a Crystalline Molecular Flask"
K. Ikemoto, Y. Inokuma, M. Fujita
J. Am. Chem. Soc. 2011, 133, 16806-16808.
"Shedding Light on Hidden Reaction Pathways in Radical Polymerization by a Porous Coordination Network"
Y. Inokuma, S. Nishiguchi, K. Ikemoto, M. Fujita
Chem. Commun. 2011, 47, 12113-12115.
"Crystalline Molecular Flasks"
Y. Inokuma, M. Kawano, M. Fujita
Nature Chem. 2011, 3, 349-358.
"A Molecular Capsule Network: Guest Encapsulation and Control of Diels–Alder Reactivity"
Y. Inokuma, S. Yoshioka, M. Fujita
Angew. Chem. Int. Ed. 2010, 49, 8912-8914.
"Networked Molecular Cages as Crystalline Sponges for Fullerenes and Other Guests"
Y. Inokuma, T. Arai, M. Fujita
Nature Chem. 2010, 2, 780-783.
(Highlighted by "C&EN", ACS)
"The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask"
K. Ikemoto, Y. Inokuma, M. Fujita
Angew. Chem. Int. Ed. 2010, 49, 5750-5752.
"The Catalytic Z to E Isomerization of Stilbenes in a Photosensitizing Porous Coordination Network"
K. Ohara, Y. Inokuma, M. Fujita
Angew. Chem. Int. Ed. 2010, 49, 5507–5509.
"Regioselective Huisgen Cycloaddition within Porous Coordination Networks"
T. Kawamichi, Y. Inokuma, M. Fujita
Angew. Chem. Int. Ed. 2010, 49, 2375–2377.
(Highlighted by "Noteworthy Chemistry", ACS)
"A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore"
K. Ohara, M. Kawano, Y. Inokuma, M. Fujita
J. Am. Chem. Soc. 2010, 132, 30–31.
Y. Inokuma, G.-H. Ning, M. Fujita
Angew. Chem. Int. Ed. 2012, 51, 2379-2381.
"Bimolecular Reaction via the Successive Introduction of Two Substrates into the Crystals of Networked Molecular Cages"
Y. Inokuma, N. Kojima, T. Arai, M. Fujita
J. Am. Chem. Soc. 2011, 133, 19691-19693.
"Diels–Alder via Molecular Recognition in a Crystalline Molecular Flask"
K. Ikemoto, Y. Inokuma, M. Fujita
J. Am. Chem. Soc. 2011, 133, 16806-16808.
"Shedding Light on Hidden Reaction Pathways in Radical Polymerization by a Porous Coordination Network"
Y. Inokuma, S. Nishiguchi, K. Ikemoto, M. Fujita
Chem. Commun. 2011, 47, 12113-12115.
"Crystalline Molecular Flasks"
Y. Inokuma, M. Kawano, M. Fujita
Nature Chem. 2011, 3, 349-358.
"A Molecular Capsule Network: Guest Encapsulation and Control of Diels–Alder Reactivity"
Y. Inokuma, S. Yoshioka, M. Fujita
Angew. Chem. Int. Ed. 2010, 49, 8912-8914.
"Networked Molecular Cages as Crystalline Sponges for Fullerenes and Other Guests"
Y. Inokuma, T. Arai, M. Fujita
Nature Chem. 2010, 2, 780-783.
(Highlighted by "C&EN", ACS)
"The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask"
K. Ikemoto, Y. Inokuma, M. Fujita
Angew. Chem. Int. Ed. 2010, 49, 5750-5752.
"The Catalytic Z to E Isomerization of Stilbenes in a Photosensitizing Porous Coordination Network"
K. Ohara, Y. Inokuma, M. Fujita
Angew. Chem. Int. Ed. 2010, 49, 5507–5509.
"Regioselective Huisgen Cycloaddition within Porous Coordination Networks"
T. Kawamichi, Y. Inokuma, M. Fujita
Angew. Chem. Int. Ed. 2010, 49, 2375–2377.
(Highlighted by "Noteworthy Chemistry", ACS)
"A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore"
K. Ohara, M. Kawano, Y. Inokuma, M. Fujita
J. Am. Chem. Soc. 2010, 132, 30–31.
List of Publications (Osuka Lab.)
"Synthesis and Properties of Boron(III)-Coordinated
Subbacteriochlorins "
S. Hayashi, E. Tsurumaki, Y. Inokuma, P. Kim, Y. M. Sung, D. Kim, A. Osuka
J. Am. Chem. Soc. 2011, 133, 4254-4256.
"Oxocyclohexadienylidene-Substituted Subporphyrins"
S. Hayashi, J. Sung, Y. Sung, Y. M. Sung, Y. Inokuma, D. Kim, A. Osuka
Angew. Chem. Int. Ed. 2011, 50, 3253-3256.
"meso-Tris(oligo-2,5-thienylene)-Substituted Subporphyrins"
S. Hayashi, Y. Inokuma, Atsuhiro Osuka
Org. Lett. 2010, 12, 4148-4151.
"meso-Trifluoromethyl-substituted Subporphyrin from Ring-splitting Reaction of meso-Trifluoromethyl-substituted [32]Heptaphyrin(1.1.1.1.1.1.1)"
R. Sakamoto, S. Saito, S. Shimizu, Y. Inokuma, N. Aratani, A. Osuka
Chem. Lett. 2010, 39, 439-441.
"meso-Trialkyl-substituted Subporphyrins"
S. Hayashi, Y. Inokuma, S. Easwaramoorthi, K. S. Kim, D. Kim, A. Osuka
Angew. Chem. Int. Ed. 2010, 49, 321–324.
"Versatile Photophysical Properties of meso-Aryl Substituted Subporphyrins: Dipolar and Octupolar Charge-Transfer Interactions"
S. Easwaramoorthi, J.-Y. Shin, S. Cho, P. Kim, Y. Inokuma, E. Tsurumaki, A. Osuka, D. Kim
Chem. Eur. J. 2009, 15, 12005–12017.
"Capped Subporphyrins"
Y. Inokuma, A. Osuka
Chem. Eur. J. 2009, 15, 6863–6876.
"1,4-Phenylene-bridged Subporphyrin–Porphyrin Dyad, Triad, and Tetrad"
Y. Inokuma, S. Hayashi, A. Osuka
Chem. Lett. 2009, 38, 206–207.
"Peripheral Hexabromination, Hexaphenylation, and Hexaethynylation of meso-Aryl- Substituted Subporphyrins"
E. Tsurumaki, Y. Inokuma, S. Easwaramoorthi, J. M. Lim, D. Kim, A. Osuka
Chem. Eur. J. 2009, 15, 237–247.
"3,3’- and 4,4’-Biphenylene-Bridged Subporphyrin Dimers"
Y. Inokuma, A. Osuka
Org. Lett. 2008, 10, 5561–5564.
"Unambiguous Identification of Möbius Aromaticity for meso-Aryl-Substituted [28]Hexaphyrins(1.1.1.1.1.1)"
J. Sankar, S. Mori, S. Saito, H. Rath, M. Suzuki, Y. Inokuma, H. Shinokubo, K. S. Kim, Z. S. Yoon, J.-Y. Shin, J. M. Lim, Y. Matsuzaki, O. Matsushita, A. Muranaka, N. Kobayashi, D. Kim A. Osuka
J. Am. Chem. Soc. 2008, 130, 13568–13579.
"meso-(4-(N,N-Dialkylamino)phenyl)-Substituted Subporphyrins: Remarkably Perturbed Absorption Spectra and Enhanced Fluorescence by Intramolecular Charge Transfer Interactions"
Y. Inokuma, S. Easwaramoorthi, Z. S. Yoon, D. Kim, A. Osuka
J. Am. Chem. Soc. 2008, 130, 12234–12235.
"Effective Expansion of the Subporphyrin Chromophore Through Conjugation with meso-Oligo(1,4-phenyleneethynylene) Substituents: Octupolar Effect on Two-Photon Absorption"
Y. Inokuma, S. Easwaramoorthi, S. Y. Jang, K. S. Kim, D. Kim, A. Osuka
Angew. Chem. Int. Ed. 2008, 47, 4840–4843.
"Synthesis and Characterization of meso-Aryl-Substituted Subchlorins"
E. Tsurumaki, S. Saito, K. S. Kim, J. M. Lim, Y. Inokuma, D. Kim, A. Osuka
J. Am. Chem. Soc. 2008, 130, 438–439.
"Complementary Face-to-Face Dimer Formation From meso-Aryl Subporphyrins Bearing a 2-Carboxyphenyl Group"
Y. Inokuma, A. Osuka
Chem. Commun. 2007, 2938–2940.
"meso-Aryl-Substituted Subporphyrins: Synthesis, Structures, and Large Substituent Effects on Their Electronic Properties"
Y. Inokuma, Z. S. Yoon, D. Kim, A. Osuka
J. Am. Chem. Soc. 2007, 129, 4747–4761.
"Tribenzosubporphines: Synthesis and Characterization"
Y. Inokuma, J. H. Kwon, T. K. Ahn, M.-C. Yoon, D. Kim, A. Osuka
Angew. Chem. Int. Ed. 2006, 45, 961–964.
"Enlarged π-Electronic Network of a meso-meso, β-β, β-β Triply Linked Dibenzoporphyrin Dimer that Exhibits a Large Two-Photon Absorption Cross Section"
Y. Inokuma, N. Ono, H. Uno, D. Y. Kim, S. B. Noh, D. Kim, A. Osuka
Chem. Commun. 2005, 3782–3784.
"A Doubly N-Fused Benzohexaphyrin and Its Rearrangement to a Fluorescent Macrocycle upon DDQ Oxidation"
Y. Inokuma, T. Matsunari, N. Ono, H. Uno, A. Osuka
Angew. Chem. Int. Ed. 2005, 44, 1856–1860.
"meso-Porphyrinyl-Substituted Porphyrin and Expanded Porphyrins"
Y. Inokuma, A. Osuka
Org. Lett. 2004, 6, 3663–3666.
Subbacteriochlorins "
S. Hayashi, E. Tsurumaki, Y. Inokuma, P. Kim, Y. M. Sung, D. Kim, A. Osuka
J. Am. Chem. Soc. 2011, 133, 4254-4256.
"Oxocyclohexadienylidene-Substituted Subporphyrins"
S. Hayashi, J. Sung, Y. Sung, Y. M. Sung, Y. Inokuma, D. Kim, A. Osuka
Angew. Chem. Int. Ed. 2011, 50, 3253-3256.
"meso-Tris(oligo-2,5-thienylene)-Substituted Subporphyrins"
S. Hayashi, Y. Inokuma, Atsuhiro Osuka
Org. Lett. 2010, 12, 4148-4151.
"meso-Trifluoromethyl-substituted Subporphyrin from Ring-splitting Reaction of meso-Trifluoromethyl-substituted [32]Heptaphyrin(1.1.1.1.1.1.1)"
R. Sakamoto, S. Saito, S. Shimizu, Y. Inokuma, N. Aratani, A. Osuka
Chem. Lett. 2010, 39, 439-441.
"meso-Trialkyl-substituted Subporphyrins"
S. Hayashi, Y. Inokuma, S. Easwaramoorthi, K. S. Kim, D. Kim, A. Osuka
Angew. Chem. Int. Ed. 2010, 49, 321–324.
"Versatile Photophysical Properties of meso-Aryl Substituted Subporphyrins: Dipolar and Octupolar Charge-Transfer Interactions"
S. Easwaramoorthi, J.-Y. Shin, S. Cho, P. Kim, Y. Inokuma, E. Tsurumaki, A. Osuka, D. Kim
Chem. Eur. J. 2009, 15, 12005–12017.
"Capped Subporphyrins"
Y. Inokuma, A. Osuka
Chem. Eur. J. 2009, 15, 6863–6876.
"1,4-Phenylene-bridged Subporphyrin–Porphyrin Dyad, Triad, and Tetrad"
Y. Inokuma, S. Hayashi, A. Osuka
Chem. Lett. 2009, 38, 206–207.
"Peripheral Hexabromination, Hexaphenylation, and Hexaethynylation of meso-Aryl- Substituted Subporphyrins"
E. Tsurumaki, Y. Inokuma, S. Easwaramoorthi, J. M. Lim, D. Kim, A. Osuka
Chem. Eur. J. 2009, 15, 237–247.
"3,3’- and 4,4’-Biphenylene-Bridged Subporphyrin Dimers"
Y. Inokuma, A. Osuka
Org. Lett. 2008, 10, 5561–5564.
"Unambiguous Identification of Möbius Aromaticity for meso-Aryl-Substituted [28]Hexaphyrins(1.1.1.1.1.1)"
J. Sankar, S. Mori, S. Saito, H. Rath, M. Suzuki, Y. Inokuma, H. Shinokubo, K. S. Kim, Z. S. Yoon, J.-Y. Shin, J. M. Lim, Y. Matsuzaki, O. Matsushita, A. Muranaka, N. Kobayashi, D. Kim A. Osuka
J. Am. Chem. Soc. 2008, 130, 13568–13579.
"meso-(4-(N,N-Dialkylamino)phenyl)-Substituted Subporphyrins: Remarkably Perturbed Absorption Spectra and Enhanced Fluorescence by Intramolecular Charge Transfer Interactions"
Y. Inokuma, S. Easwaramoorthi, Z. S. Yoon, D. Kim, A. Osuka
J. Am. Chem. Soc. 2008, 130, 12234–12235.
"Effective Expansion of the Subporphyrin Chromophore Through Conjugation with meso-Oligo(1,4-phenyleneethynylene) Substituents: Octupolar Effect on Two-Photon Absorption"
Y. Inokuma, S. Easwaramoorthi, S. Y. Jang, K. S. Kim, D. Kim, A. Osuka
Angew. Chem. Int. Ed. 2008, 47, 4840–4843.
"Synthesis and Characterization of meso-Aryl-Substituted Subchlorins"
E. Tsurumaki, S. Saito, K. S. Kim, J. M. Lim, Y. Inokuma, D. Kim, A. Osuka
J. Am. Chem. Soc. 2008, 130, 438–439.
"Complementary Face-to-Face Dimer Formation From meso-Aryl Subporphyrins Bearing a 2-Carboxyphenyl Group"
Y. Inokuma, A. Osuka
Chem. Commun. 2007, 2938–2940.
"meso-Aryl-Substituted Subporphyrins: Synthesis, Structures, and Large Substituent Effects on Their Electronic Properties"
Y. Inokuma, Z. S. Yoon, D. Kim, A. Osuka
J. Am. Chem. Soc. 2007, 129, 4747–4761.
"Tribenzosubporphines: Synthesis and Characterization"
Y. Inokuma, J. H. Kwon, T. K. Ahn, M.-C. Yoon, D. Kim, A. Osuka
Angew. Chem. Int. Ed. 2006, 45, 961–964.
"Enlarged π-Electronic Network of a meso-meso, β-β, β-β Triply Linked Dibenzoporphyrin Dimer that Exhibits a Large Two-Photon Absorption Cross Section"
Y. Inokuma, N. Ono, H. Uno, D. Y. Kim, S. B. Noh, D. Kim, A. Osuka
Chem. Commun. 2005, 3782–3784.
"A Doubly N-Fused Benzohexaphyrin and Its Rearrangement to a Fluorescent Macrocycle upon DDQ Oxidation"
Y. Inokuma, T. Matsunari, N. Ono, H. Uno, A. Osuka
Angew. Chem. Int. Ed. 2005, 44, 1856–1860.
"meso-Porphyrinyl-Substituted Porphyrin and Expanded Porphyrins"
Y. Inokuma, A. Osuka
Org. Lett. 2004, 6, 3663–3666.
Accounts and Reviews
"Chemistry in Porous Coordination Networks"
M. Fujita, Y. Inokuma
Catalysts and Catalysis 2010, 52, 172–177.
"Subporphyrins: Emerging Contracted Porphyrins with Aromatic 14π-Electronic Systems and Bowl-Shaped Structures: Rational and Unexpected Synthetic Routes"
Y. Inokuma, A. Osuka
Dalton Trans. 2008, 2517–2526.
M. Fujita, Y. Inokuma
Catalysts and Catalysis 2010, 52, 172–177.
"Subporphyrins: Emerging Contracted Porphyrins with Aromatic 14π-Electronic Systems and Bowl-Shaped Structures: Rational and Unexpected Synthetic Routes"
Y. Inokuma, A. Osuka
Dalton Trans. 2008, 2517–2526.